Preparation of a uniform poly(methyl methacrylate) macromonomer and its polymerization
作者:
Koichi Hatada,
Takafumi Nishiura,
Tatsuki Kitayama,
Shuji Hirotani,
期刊:
Macromolecular Rapid Communications
(WILEY Available online 1997)
卷期:
Volume 18,
issue 1
页码: 37-43
ISSN:1022-1336
年代: 1997
DOI:10.1002/marc.1997.030180106
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractSyndiotactic poly(methyl methacrylate) (st‐PMMA) macromonomer having methacryloyl end group was prepared from st‐PMMA living anion and separated into uniform macromonomers by means of supercritical fluid chromatography. A uniform macromonomer with the degree of polymerization of 32 was polymerized radically in benzene at 60°C. The uniform dimer, trimer and tetramer of the uniform macromonomer were isolated from the polymerization product by means of gel‐permeation chromatography (GPC). The intrinsic viscosity ([η]) in tetrahydrofuran of these uniform comblike polymers was determined by GPC/differential viscometric analysis. The plot of logarithmic [η]against logarithmic molecular weight indicated that the trimer and tetramer assume a little shrinking molecular shape as compared with the unimer a
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