Oxidation‐Reduction Kinetics in MnO
作者:
I. BRANSKY,
N. M. TALLAN,
J. M. WIMMER,
M. GVISHI,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1971)
卷期:
Volume 54,
issue 1
页码: 26-30
ISSN:0002-7820
年代: 1971
DOI:10.1111/j.1151-2916.1971.tb12161.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
The oxidation‐reduction kinetics of MnO in CO/CO2atmospheres at 1230°C were measured by gravimetric and electrical conductivity techniques. The dependence of the kinetics on time, inert gas dilution, total pressure, and specimen thickness indicates that the kinetics are controlled by a slow surface reaction step. Attempts to analyze the data quantitatively using equations for linear heat flow in a solid with a radiation boundary condition were unsuccessf
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