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Synthesis of Hyperbranched Platinum-Poly(yne) Polymers by Self Polycondensation

 

作者: Kiyotaka Onitsuka,   Nobuaki Ohshiro,   Masanori Fujimoto,   Fumie Takei,   Shigetoshi Takahashi,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 159-166

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038260

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A hyperbranched polymer constructed by platinum-acetylide units has been synthesized by self polycondensation of a dinuclear platinum complex having one terminal acetylene and two platinum-chloride groups as an AB2monomer in the presence of a copper catalyst in amine. The hyperbranched polymer is soluble in common organic solvents and characterized by means of spectral analyses and GPC.

 

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