Photochromic Behavior of Isochromenes (1H-Benzopyrans) as Studied by Transient Absorption Spectroscopy
作者:
Eisuke Haba,
Katsunori Segawa,
Hirochika Sakuragi,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 345,
issue 1
页码: 221-226
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023922
出版商: Taylor & Francis Group
关键词: Isochromenes;Photochromism;Transient absorption spectroscopy;Two-color laser photolysis
数据来源: Taylor
摘要:
3-Phenyl- and 3-(2-naphthyl)isochromene show light-intensity-dependent photochromic behavior; the excitations with low- and high-intensity laser pulses produce isomeric open forms by way of one-photon and two-photon processes, respectively, their lifetimes being in the hundred-nanosecond and hundred-microsecond orders, respectively.
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