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Polaron Band Model and Its Application to Ce&sngbnd;S Semiconductors

 

作者: J. Appel,   S. W. Kurnick,  

 

期刊: Journal of Applied Physics  (AIP Available online 1961)
卷期: Volume 32, issue 10  

页码: 2206-2210

 

ISSN:0021-8979

 

年代: 1961

 

DOI:10.1063/1.1777044

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The low‐lying eigenstates of the ``large polarons'' have been calculated by several authors for arbitrary strengths of the electron lattice interaction &agr;. However, if &agr; > 1 the large polaron picture becomes questionable, since for finite temperatures the polaron eigenstates may be strongly affected by the presence of thermal phonons; then a new approach to the polaron theory is applicable which takes into account the atomicity of the lattice and the presence of thermal phonons and which results in the ``small polaron'' picture. The eigenstates of small polarons depend onT. If the eigenstates form a band, the bandwidth is a function ofT, and the eigenstates near the band extremum can be expressed in terms of aT‐dependent effective mass. From measurements of the high‐ and low‐frequency dielectric constants, of the temperature dependence of the Seebeck coefficient, and of the electronic mobility, it appears that the eigenstates of the electronic charge carriers in Ce&sngbnd;S semiconductors may be adequately described by the small polaron picture.

 

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