首页   按字顺浏览 期刊浏览 卷期浏览 Influence of shear on a lamellar triblock copolymer near the order–disorder transition
Influence of shear on a lamellar triblock copolymer near the order–disorder transition

 

作者: T. Tepe,   D. A. Hajduk,   M. A. Hillmyer,   P. A. Weimann,   M. Tirrell,   F. S. Bates,   K. Almdal,   K. Mortensen,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 5  

页码: 1147-1171

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550819

 

出版商: The Society of Rheology

 

关键词: Copolymer, lamellar triblock;Block copolymer;Triblock copolymer;Neutron scattering;SANS

 

数据来源: AIP

 

摘要:

The effects of a large strain (600%) reciprocating steady shear on the lamellar orientation and the order–disorder transition of a nearly symmetric poly(ethylene propylene)–poly(ethylethylene)–poly(ethylene propylene) (PEP–PEE–PEP) triblock copolymer have been studied using small-angle neutron scattering and rheological measurements. Shearing in the ordered state produced parallel lamellae under all steady-state conditions investigated, and the lamellar-to-disorder transition temperature decreased dramatically with increasing shear rate. Both phenomena are qualitatively different from the documented behavior of PEP–PEE diblock copolymers. However, cooling the disordered material while shearing at a relatively low deformation rate initially induces perpendicular lamellae, analogous to the diblock response. These observations are considered in the context of theory and other experimental studies.

 

点击下载:  PDF (407KB)



返 回