On Temperature Dependence of Charge Photogeneration in Holecular Crystals
作者:
Jan Kalibowski,
Jan Godlewski,
PiergiulioDi Marco,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 217,
issue 1
页码: 211-216
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208046903
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A simple analytical expression for the charge photogeneration yield (φ) is derived which is based on the Onsager theory of geminate recombination. The expression shows non-Arrhenius temperature (T) dependence φ∼exp(-A/½) with A=2(ezα/4πϵ ϵk)½, where α is a characteristic parameter in the spatial (r) distribution function of thermalized electron-hole pairs g(r) = = (α/4πr2)exp(-αr). The values of α obtained on its basis from the literature experimental data for anthracene crystals are interpreted in terms of collision cross section for primary carriers. The discrete photon energy dependence of α can be explained by crystal anisotropy for the carrier motion.
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