Kinetic study of stilbene synthesis with benzyltriphenylphosphonium bromide as phase transfer catalyst
作者:
Maw‐Ling Wang,
Shaw‐Rong Lay,
Jing‐Jer Jwo,
期刊:
Journal of the Chinese Institute of Engineers
(Taylor Available online 1989)
卷期:
Volume 12,
issue 3
页码: 293-300
ISSN:0253-3839
年代: 1989
DOI:10.1080/02533839.1989.9677164
出版商: Taylor & Francis Group
关键词: stilbene;phase transfer catalysis
数据来源: Taylor
摘要:
A kinetic study of the Wittig reaction for synthesizing stilbene is carried out by reacting benzaldehyde (C6H5CHO) with benzyltri‐phenylphosphonium bromide (BTPPB) in the NaOH(aq)/CH2Cl2(org) two‐phase reaction system. The rate of reaction depends on the agitation speed, the temperature and the concentrations of C6H5CHO, BTPPB, and NaOH. When the agitation speed is low, the reaction is highly affected by interface diffusion. The reactant rate constant, based on theSN2 substitution mechanism and the activation energy are also determined. It is found that the activation energy obtained from the present study (Ea=11.97 kcal/mole) is less than that of the previously documented data (Ea=12.984 kcal/mole) in which benzyltriphenylphosphonium chloride (BTPPC) was used as a phase transfer catalyst.
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