The Organometallic Chemistry of Carbon Suboxide
作者:
Gastone Paiaro,
Luciano Pandolfo,
期刊:
Comments on Inorganic Chemistry
(Taylor Available online 1991)
卷期:
Volume 12,
issue 4
页码: 213-235
ISSN:0260-3594
年代: 1991
DOI:10.1080/02603599108053475
出版商: Taylor & Francis Group
关键词: carbon suboxide;organometallic derivatives;complexes;ketenyl compounds;ketenyl reactivity
数据来源: Taylor
摘要:
Carbon suboxide, C3, O2, reacts with a great variety of organometallic compounds. With organo-silicon and aluminium compounds it reacts with the C˭O moiety, giving sililation and carboalumination reactions. Insertion reactions of C˭C are performed with compounds having M-H, M-OR, M-NR2, M-PR2bonds (M ≠ Si, Al), giving mono-metal derivatives (ketenyl) or di-metal derivatives of acil groups (amides, esthers, phospides). The coordination of C˭O or C˭C to transition metal complexes, the formation of allenic compounds and the decarbonylation reactions allow the synthesis of a series of particular metal derivatives (ketenyl, ketenylidene and carbonyl complexes) which, in some cases, present a peculiar reactivity.
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