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Studies of benzylisoquinolines. Comparison of the reactivity of the methylene group in 1‐benzyl and 4‐benzylisoquinolines

 

作者: Claude Vaccher,   Pascal Berthelot,   Monique Devergnies,   Michel Debaert,   Jean‐Paul Bonte,   Claude Viel,  

 

期刊: Journal of Heterocyclic Chemistry  （WILEY Available online 1989）
卷期: Volume 26, issue 3  

页码: 811-815

 

ISSN:0022-152X

 

年代: 1989

 

DOI:10.1002/jhet.5570260356

 

出版商: Wiley‐Blackwell

 

数据来源: WILEY

 

摘要:

AbstractWhile examining the oxidation of 4‐benzylisoquinolines to the corresponding 4‐benzoylisoquinolines as well as the reactivity of these ketones towards hydroxylamine, reduction reagents and Grignard's reagents, there was found a definite difference in the behavior of the methylene group for these compounds as compared to that of papaverine (1‐benzylisoquinol

 

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