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Structural chemistry, magnetism and119Sn Mo¨ssbauer spectroscopy of ternary compounds REMn6Sn6(RE=Pr,Nd,Sm)

 

作者: F. Weitzer,   A. Leithe‐Jasper,   K. Hiebl,   P. Rogl,   Qinian Qi,   J. M. D. Coey,  

 

期刊: Journal of Applied Physics  (AIP Available online 1993)
卷期: Volume 73, issue 12  

页码: 8447-8450

 

ISSN:0021-8979

 

年代: 1993

 

DOI:10.1063/1.353416

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Ternary compounds (Pr,Nd,Sm)Mn6Sn6have been synthesized by argon arc melting starting from the pure elements. All compounds were found to be isotypic with HoFe6Sn6(space groupImmm‐D2h25, no. 71;Z=6). The HoFe6Sn6type is a stacking variant composed of slabs of the HfFe6Ge6type and of the ScFe6Ga6type. The compounds order ferrimagnetically slightly above room temperature exhibiting a strong magnetocrystalline anisotropy. The119Sn Mo¨ssbauer spectra at 15 and 293 K were fitted with five magnetic sextets, with hyperfine fields ranging from 12 to 32 T at 15 K.

 

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