Structural chemistry, magnetism and119Sn Mo¨ssbauer spectroscopy of ternary compounds REMn6Sn6(RE=Pr,Nd,Sm)
作者:
F. Weitzer,
A. Leithe‐Jasper,
K. Hiebl,
P. Rogl,
Qinian Qi,
J. M. D. Coey,
期刊:
Journal of Applied Physics
(AIP Available online 1993)
卷期:
Volume 73,
issue 12
页码: 8447-8450
ISSN:0021-8979
年代: 1993
DOI:10.1063/1.353416
出版商: AIP
数据来源: AIP
摘要:
Ternary compounds (Pr,Nd,Sm)Mn6Sn6have been synthesized by argon arc melting starting from the pure elements. All compounds were found to be isotypic with HoFe6Sn6(space groupImmm‐D2h25, no. 71;Z=6). The HoFe6Sn6type is a stacking variant composed of slabs of the HfFe6Ge6type and of the ScFe6Ga6type. The compounds order ferrimagnetically slightly above room temperature exhibiting a strong magnetocrystalline anisotropy. The119Sn Mo¨ssbauer spectra at 15 and 293 K were fitted with five magnetic sextets, with hyperfine fields ranging from 12 to 32 T at 15 K.
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