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Ionic Distribution Coefficients and Electrochemical Potentials

 

作者: J. Badoz-lambling,   J. Desbarres,   A. Quéré,  

 

期刊: Analytical Letters  （Taylor Available online 1972）
卷期: Volume 5, issue 10  

页码: 729-735

 

ISSN:0003-2719

 

年代: 1972

 

DOI:10.1080/00032717208064354

 

出版商: Taylor & Francis Group

 

关键词: Distribution coefficients;partition coefficients;medium effects;electrochemical potential;pH scales in different solvents.

 

数据来源: Taylor

 

摘要:

A novel “electrochemical ionic distribution coefficient”, i is defined based on Guggenheim's electrochemical potential concept. i correlates the activities of a given ion in different solvents. The definition of i is entirely consistent with the practice to interrelate chemical equilibrium constants in various solvents via the classical ionic distribution coefficient i.

 

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