Effect of Bi2O3on Impurity Ion Distribution and Electrical Resistivity of Li‐Zn Ferrites
作者:
Keith G. Brooks,
Yolande Berta,
Vasantha R. W. Amarakoon,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 11
页码: 3065-3069
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb04387.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
Preventing the incorporation of impurities in Li‐Zn ferrite grains during sintering is essential for production of ceramics withreproduciblemagnetic and electrical properties. Li‐Zn ferrites of composition Li0.3Zn0.4Mn0.05Fe2.25O4were prepared with Bi2O3and borosilicate sintering additives. The distribution of impurity ions in the sintered ferrites was investigated using transmission electron microscopy (TEM) coupled with energy dispersive spectroscopy (EDS). Ceramics prepared with Bi2O3contained Si, Ca, and S impurities, located at grain boundaries and triple point regions. The low viscosity and good wetting properties of the Bi2O3and to a lesser extent the borosilicate liquid phase allowed impurities to be selectively removed from the growing ferrite phase during sintering, thus improving sample resistivit
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