Photoacoustic Spectroscopic Studies of Mono-Substituted Naphthalene Molecules
作者:
R.K. Garg,
Pardeep Kumar,
R.S. Ram,
Z.H. Zaidi,
期刊:
Spectroscopy Letters
(Taylor Available online 1998)
卷期:
Volume 31,
issue 5
页码: 1013-1023
ISSN:0038-7010
年代: 1998
DOI:10.1080/00387019808003279
出版商: Taylor & Francis Group
关键词: Photoacoustic Spectroscopy;Polycyclic aromatic hydrocarbons;Naphthols;Singlet-Triplet Transitions;CNDO Calculations
数据来源: Taylor
摘要:
The present paper deals with the Photoacoustic (PA) studies of mono-substituted (hydroxy) naphthalene molecules, namely 1-naphthol and 2-naphthol in boric acid glass in the region 250–400 nm. The electronic transitions of these molecules observed experimentally, have been interpreted using the optimised geometries and CNDO/S-CI method. Assignments of observed electronic transitions are made on the basis of singlet-singlet and singlet-triplet transitions. The PA spectra of 1-naphthol and 2- Maphthol are compared with its parent molecule i.e. naphthalene molecule, in terms of charge transfer character of -OH group and polarization of molecules. It is observed that the non-radiative transitions in mono-substituted naphthalene molecules shift towards the higher wavelength region when compared with naphthalene molecule, which may be attributed to increase in the charge density in the substituted ring.
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