Thermal behavior of vinylidene chloride—methyl acrylate copolymers
作者:
B.G. Landes,
W.J. Raich,
P.T. De Lassus,
I.R. Harrison,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1983)
卷期:
Volume 22,
issue 5-6
页码: 747-762
ISSN:0022-2348
年代: 1983
DOI:10.1080/00222348308245753
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The thermal behavior of random copolymers of vinylidene chloride-methyl acrylate (VDC-MA) was monitored with differential scanning calorimetry. The effects of composition, annealing, and heating rate on the copolymer melting process were studied. Increasing levels of comonomer decreased the crystalline melting point and percent crystallinity of the copolymers. A combination of information obtained from heating rate and small-angle x-ray scattering studies led to a model of the melting behavior of PVDC and its copolymers. Apparently a simultaneous melting/recrystallization phenomenon occurs in these materials during heating.
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