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Existence of Detonations for Large Values of the Rate Parameter

 

作者: W. W. Wood,  

 

期刊: Physics of Fluids(00319171)  (AIP Available online 1963)
卷期: Volume 6, issue 8  

页码: 1081-1090

 

ISSN:0031-9171

 

年代: 1963

 

DOI:10.1063/1.1706865

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Recent investigations of idealized Navier‐Stokes detonation structure have left unresolved the existence and nature of flow solutions in the case of very fast reactions. By formulating the problem explicitly in terms of a specified initial state and a specified hot boundary mass velocitywP(relative to the unreacted explosive), it is shown that suitable ``steady'' flows exist in all cases, providing that a rarefaction wave or a slower moving shock wave is allowed to follow the detonation front.An initial‐state parameter &Ggr;0, involving the reaction‐rate ``pre‐exponential factor'' and the thermal conductivity, is defined, as well as an associated critical value &Ggr;u(CJ), which depends on the heat capacity ratio, and the enthalpy and activation energy of the reaction. If &Ggr;0< &Ggr;u(CJ), then for smallwPthe predicted flow is the Chapman‐Jouguet (CJ) detonation followed by a rarefaction. AswPis increased through the CJ mass velocitywC J, the flow changes continuously to increasingly overdriven detonations. If &Ggr;0> &Ggr;u(CJ), then for smallwPthe predicted flow is a weak detonation whose velocityDdepends on &Ggr;0, followed by a rarefaction. AswPis increased through the corresponding weak detonation mass velocityw(&Ggr;0), the flow becomes the same weak detonation followed by a slower moving shock wave. With continued increase ofwPthis shock velocity increases until, at a certain value ofwP, it becomes equal to the weak detonation velocity. At still largerwP, the flow changes continuously into an overdriven strong detonation.Both unimolecular and bimolecular kinetics are considered. So‐called ``reasonable'' values of the unimolecular parameters lead to the possibility of the flows involving weak detonations, but as noted by Hirschfelder, Curtiss,et al., the conditions are then such as to require a quasi‐unimolecular mechanism to become bimolecular, due for example to depletion of the activated state. When bimolecular kinetics are considered, reasonable parameter values appear to exclude the weak detonation flows.

 

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