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Photopolymerization of Acrylonitrile with the Isopropanol-Ag(I) System as Initiator

 

作者: T.partha Sarathy,   K.Nageswar Rao,   B. Sethuram,   T.Navaneeth Rao,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1986）
卷期: Volume 23, issue 8  

页码: 955-961

 

ISSN:0022-233X

 

年代: 1986

 

DOI:10.1080/00222338608081103

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Photopolymerization of acrylonitrile was studied with the isopropanol-Ag(I) system as initiator in aqueous medium. The rate of polymerization increased with time and reached a steady state within 10 min. The rate of polymerization was found to be proportional to [acrylonitrile]1.5, [Ag(I)]0.5, and [isopropanol]0.5. A probable mechanism consistent with the observed results is proposed and discussed.

 

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