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Electromemical Sample Contamination from Aqueous V (III) Oxygen Scrubbers

 

作者: PaulaM. Deano,   J.W. Robinson,   RobertJ. Gale,  

 

期刊: Analytical Letters  (Taylor Available online 1984)
卷期: Volume 17, issue 6  

页码: 447-450

 

ISSN:0003-2719

 

年代: 1984

 

DOI:10.1080/00032718408065292

 

出版商: Taylor & Francis Group

 

关键词: Oxygen scrubbers;stripping voltammetry

 

数据来源: Taylor

 

摘要:

We recommend that attention be given to the possibility of sample contamination in trace level electrochemical experiments when classical aqueous oxygen scrubbers are used. Although fresh electrolyte or water pre-saturators can be used to minimize ion carryover by aerosol spray, mercury vapor is still present in the gas stream. Many electrochemists now use solid catalysts (such as BASF R3-11, Badische Anilin and Soda-Fabrik), and their use, or that of pre-purified gases, are recommended to avoid such problems with purge gases in trace electroanalyses.

 

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