Determination of Cobalt in Biological Samples by Inductively Coupled Plasma Atomic Emission Spectrometry After Preconcentration by Extraction With 1,5-bis(Di-2-Pyridylmethylene)thiocarbonhydrazide
作者:
G. Collado Gomez,
A. Garcia de Torres,
J.M. Cano Pavon,
C. Bosch Ojeda,
期刊:
Analytical Letters
(Taylor Available online 1995)
卷期:
Volume 28,
issue 7
页码: 1181-1196
ISSN:0003-2719
年代: 1995
DOI:10.1080/00032719508000337
出版商: Taylor & Francis Group
关键词: Solvent extraction;inductively coupled plasma emission spectrometry;cobalt;biological samples
数据来源: Taylor
摘要:
A method is proposed for the solvent extraction of cobalt using 1,5-bis(di-2-pyridylmethylene) thiocarbonohydrazide (DPTH) as extractant. The optimum extraction conditions were evaluated from a critical study of the effect of pH. concentration of extractant, shaking time and ionic strength. The maximum volume ratio of the aqueous to organic phase was 30:1 for a single-stage extraction of 99-100 % of the metal ion. The detection limit is 0.9 ng/ml cobalt, and the calibration is linear from 0.9 to 1000 ng/ml. The effect of interferences was studied and no interferences from the elements commonly found in biological materials were observed. The extraction method was applied to the determination of cobalt in some biological materials using inductively coupled plasma atomic emission spectrometry (ICP-AES).
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