A kinetic approach for the mechanism of malachite green‐peroxydisulphate reaction in aqueous solution
作者:
T. Mushinga,
S. B. Jonnalagadda,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1992)
卷期:
Volume 24,
issue 1
页码: 41-49
ISSN:0538-8066
年代: 1992
DOI:10.1002/kin.550240106
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe oxidation kinetics of malachite green (MG) with peroxydisulphate ion (PDS) were investigated by monitoring the absorbance change at 618 nm, in aqueous solutions under buffered and unbuffered conditions. Under both conditions, the reaction had first order dependence on reductant and a fractional order (one half) dependence on the oxidant. The stoichiometric ratio between MG and PDS was 1:2. The reaction had a negative salt effect. Reaction rates were enhanced under both high or low pH relative to neutral conditions. A plausible mechanism is proposed.
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