AGGREGATION OF COMPLEXES FORMED IN THE EXTRACTION OF SELECTED METAL CATIONS BY P,P'-DI(2-ETHYLHEXYL) METHANEDIPHOSPHONIC ACID*
作者:
R. Chiarizia,
V. Urban,
P. Thiyagarajan,
A.W. Herlinger,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1999)
卷期:
Volume 17,
issue 1
页码: 113-132
ISSN:0736-6299
年代: 1999
DOI:10.1080/07360299908934603
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The aggregation of several metal complexes formed during solvent extraction with P,P'-di(2-ethylhexyl) methanediphosphonic acid, H2DEH[MDP], in deuterated toluene, has been investigated by small angle neutron scattering (SANS). The SANS results show that the Ca(II)-, Al(ni)-, La(III)- and Nd(III)-H2DEH[MDP] compounds exhibit little or no tendency to aggregate. Uranyl complexes of H2DEH[MDP] at high metal loading form small aggregates with an aggregation number of approximately 14. This behavior is in sharp contrast with the Th(IV)-H2DEH[MDP] system which forms large aggregates in the organic phase under high metal loading conditions. The aggregation behavior of the various metal-H2DEH[MDP] compounds is discussed in light of the information obtained from earlier solvent extraction, vapor pressure osmometry, and infrared spectroscopy studies.
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