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Cycloketonization and linear polyketonization ofα,ω-dicarboxylic acids

 

作者: A.L.Liberman,   T.V.Vasina,   Z.Z.Novikova,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 20, issue 9  

页码: 1809-1812

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00854395

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.When cadmium salts of dicarboxylic acids (adipic, suberic, and sebacic) are heated, two reactions compete: cycloketonization and linear polyketonization. For adipate the predominant reaction direction is cycloketonization; for sebacate the only reaction direction is linear polyketonization; suberate reacts in both directions with commensurate rates.2.The cadmium salts of polyketodicarboxylic acids formed are apparently oxidized by cadmium oxide under the reaction conditions at theα-hydrogen atom to the carbonyl group. As a result, the chains of the salts of polyketodicarboxylic acids are coupled together into space lattices

 

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