Étude chimique et cinétique de l'oxydation homogène en phase gazeuse d'alcanes légers. II. Propane et mécanisme généralisé
作者:
B. Vogin,
F. Baronnet,
G. Scacchi,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1991)
卷期:
Volume 69,
issue 1
页码: 43-61
ISSN:0008-4042
年代: 1991
DOI:10.1139/v91-008
出版商: NRC Research Press
数据来源: NRC
摘要:
An experimental study of the homogeneous gas phase oxidation of propane at 350 °C and subatmospheric pressure has been performed in order to identify and to measure the major primary products of the reaction. The experimental results have been interpreted by a chain radical mechanism, deduced from these results and from estimates of the rate constants for the elementary steps obtained by the methods of Thermochemical Kinetics. The proposed elementary steps are discussed and compared with the experimental observations. The results that we have obtained and their interpretation are compared with a similar detailed investigation performed on the oxidation of isobutane. As in the case of isobutane, two parallel reaction pathways appear, a dominant one leading to the conjugated alkene (propylene) and another one leading to the epoxide of this olefin (here propylene oxide). The oxidation of isobutane and that of propane appear to be quite similar, which corroborates the results that we have obtained.Keywords: oxidation, kinetics, reaction mechanism, propane, thermochemical kinetics.
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