The stochastic geometry of polymer crystallization processes1
作者:
A. Micheletti,
V. Capasso,
期刊:
Stochastic Analysis and Applications
(Taylor Available online 1997)
卷期:
Volume 15,
issue 3
页码: 355-373
ISSN:0736-2994
年代: 1997
DOI:10.1080/07362999708809481
出版商: Marcel Dekker, Inc.
数据来源: Taylor
摘要:
The process of crystallization of polyrners may be modelled as a spatially structured counting process, whose intensity kernel depends upon the available free volume. Due to the effect of impingement, an explicit expression for the stochastic occupied volume is difficult to obtain, while derivations of its expected value have been provided since the pioneering work of Kolmogorov and Avrami, in use of chemical engineers. In this paper we provide two theorems which, by the use of stochastic geometry, ensure local and global convergence of the stochastic growth process to its expected value, justifing so the use of deterministic models to predict the results of real experiments.
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