X-ray study of the backbone conformation of a comb-shaped polyacrylate with nematic to smectic A phase transitions
作者:
WimG. Bouwman,
WimH. De Jeu,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 5
页码: 853-856
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408027855
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The change in backbone conformation from prolate to oblate upon going from the re-entrant nematic to the smectic Adphase is studied in a comb-shaped polyacrylate by measuring the mosaicity of the sample in the smectic phase with X-ray scattering. In combination with the possibility of aligning the director in both nematic phases, the results indicate that the conformational change takes place in the re-entrant nematic phase upon approaching the smectic Adphase.
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