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Dependence of the third-order coefficients in Landau free energies forbcc→fccstructural transition on hydrogen concentration in zirconium hydrides

 

作者: Yuh Ashida,   Masahiro Yamamoto,   Shizuo Naito,   Mahito Mabuchi,   Tomoyasu Hashino,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 82, issue 3  

页码: 1072-1079

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.365873

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Young’s modulusEand the modulus of rigidityGof zirconium hydridesZrHx(0.9⩽x⩽1.65)at 941 and 1001 K have been obtained as a function of hydrogen concentrationcby measuring resonance frequencies for bending and torsion vibrations of a polycrystalline wire. Ascincreases, observedEandGincrease in the bcc &bgr; phase, slightly increase linearly in the&bgr;+&dgr;phase, and then decrease in the fcc &dgr; phase. On the basis of a phenomenological free energy in terms of strain components taking account of space group symmetry, two types of Landau expansion of the free energies for the &bgr; phase in terms of the strain components which play an important role in the structural phase transition between the &bgr; and the &dgr; phases are examined. The observedEandGare assumed to be the same as the second-order coefficients of the free energy for the Bain distortions, which occur at the structural phase transition. The dependence of the third-order coefficients oncpermits the expanded free energies to describe the fact that the &bgr; phase is more stable than the &dgr; phase at lowc.©1997 American Institute of Physics.

 

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