Dependence of the third-order coefficients in Landau free energies forbcc→fccstructural transition on hydrogen concentration in zirconium hydrides
作者:
Yuh Ashida,
Masahiro Yamamoto,
Shizuo Naito,
Mahito Mabuchi,
Tomoyasu Hashino,
期刊:
Journal of Applied Physics
(AIP Available online 1997)
卷期:
Volume 82,
issue 3
页码: 1072-1079
ISSN:0021-8979
年代: 1997
DOI:10.1063/1.365873
出版商: AIP
数据来源: AIP
摘要:
Young’s modulusEand the modulus of rigidityGof zirconium hydridesZrHx(0.9⩽x⩽1.65)at 941 and 1001 K have been obtained as a function of hydrogen concentrationcby measuring resonance frequencies for bending and torsion vibrations of a polycrystalline wire. Ascincreases, observedEandGincrease in the bcc &bgr; phase, slightly increase linearly in the&bgr;+&dgr;phase, and then decrease in the fcc &dgr; phase. On the basis of a phenomenological free energy in terms of strain components taking account of space group symmetry, two types of Landau expansion of the free energies for the &bgr; phase in terms of the strain components which play an important role in the structural phase transition between the &bgr; and the &dgr; phases are examined. The observedEandGare assumed to be the same as the second-order coefficients of the free energy for the Bain distortions, which occur at the structural phase transition. The dependence of the third-order coefficients oncpermits the expanded free energies to describe the fact that the &bgr; phase is more stable than the &dgr; phase at lowc.©1997 American Institute of Physics.
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