Stability Constants of Cu2+, Fe3+↦ Zr4+Chelates of Ampicillin, Dopamine and α-Methyl L-Dopa in Aqueous Medium
作者:
M.G. Abd El Wahed,
M. Ayad©,
期刊:
Analytical Letters
(Taylor Available online 1984)
卷期:
Volume 17,
issue 3
页码: 205-216
ISSN:0003-2719
年代: 1984
DOI:10.1080/00032718408065279
出版商: Taylor & Francis Group
关键词: Ampicillin;Dopsmine;α -Methyl L-Dopa;Metal chelate;Protonation constant;Stability constant;Potentiometric titration.
数据来源: Taylor
摘要:
Formation constants of chelates of ampicillin, dopamine, and α -methyl L-dopa with Cu2+, Fe3+and Zr4+have been determined in aqueous medium at ionic strength of 0.1 M (KC1) using Calvin-Bjerrum technique as applied by Irving and Rossotti. Zirconium forms relatively more stable chelates with ampicillin as compared to copper and iron. However, in case of dopamine and α-methyl L-dopa the chelation with iron is the more stable. The order of stability of copper and iron is in agreement with the Irving-Villiems order. The mixed ligand chelates have been, also, investigated. The stability sequence has been found to be Cu2+< Fe3+< Zr4+
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