An Approach to the Design of Molecular Solids. A Symmetry Analysis of the Problem
作者:
JosephW. Lauher,
Yuh-Loo Chang,
FrankW. Fowler,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 211,
issue 1
页码: 99-109
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208025809
出版商: Taylor & Francis Group
关键词: hydrogen bonding;symmetry analysis;molecular design;group theory;ureas
数据来源: Taylor
摘要:
In a molecular crystal, intermolecular interactions will correspond to specific symmetry elements. If one chooses molecules carefully, one can reliably predict specific intermolecular interactions and the corresponding symmetry operations. The symmetry operations of one and two dimensional networks of molecules can be combined to form rod and layer groups respectively. In many cases of chemical interest the sequence of moving from a molecule to a one dimensional array, then on to two and three dimensions corresponds directly to the symmetry combinations leading from the point group to rod group, to layer group and on to the space group. The structures of a number of disubstituted urea derivatives were determined and are used to illustrate these ideas of molecular design.
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