Ultraviolet-Enhanced Ozonation of Organic Compounds: 1,2-Dichloroethane and Trichloroethylene as Model Substrates
作者:
Susan J. Masten,
James N. Butler,
期刊:
Ozone: Science & Engineering
(Taylor Available online 1986)
卷期:
Volume 8,
issue 4
页码: 339-353
ISSN:0191-9512
年代: 1986
DOI:10.1080/01919518608552412
出版商: Taylor & Francis Group
关键词: Ozone;Ultraviolet Radiation;Hydrogen Peroxide;Oxidation of Chlorinated Organics;1,2-Dichloroethane;Trichloroethylene;Ozone/UV Radiation;Ozone/Hydrogen Peroxide;Hydrogen Peroxide/Ultraviolet;Groundwater
数据来源: Taylor
摘要:
1,2–Dichloroethane (DCE) and trichloroethylene (TCE) were used as model compounds to study the oxidation of organic chemicals by ozone/ultraviolet radiation, ozone, and hydrogen peroxide/ultraviolet radiation. It was found that ozone/ultraviolet radiation oxidized both 1,2–dichloroethane and trichloroethylene in batch systems, at pH = 2 (phosphate buffer). At ozone concentrations in the 1 to 5 mg/L range, the reaction was first order in both ozone and substrate. At pH = 2 and initial ozone concentration 2.2–2.6 mg/L, rate constants (k)Q = 25 and 130 M-1sec-1were observed for the ozone/ultraviolet radiation oxidation of DCE and TCE, respectively. The rat e constants for ozone oxidation of DCE and TCE without ultraviolet radiation were 4.3 and 47 M-1sec-1, respectively.
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