首页   按字顺浏览 期刊浏览 卷期浏览 Rheological properties of rodlike polymers in solution. IV. Rheology of blends of nylon...
Rheological properties of rodlike polymers in solution. IV. Rheology of blends of nylon and a rodlike chain

 

作者: C. S. Kim,   G. C. Berry,  

 

期刊: Journal of Rheology  (AIP Available online 1990)
卷期: Volume 34, issue 7  

页码: 1011-1038

 

ISSN:0148-6055

 

年代: 1990

 

DOI:10.1122/1.550108

 

出版商: The Society of Rheology

 

关键词: Homogeneous blends;Rheology of blends;Rheo‐optical measurements;Retardation time;BKZ theory;Birefringence;ORGANIC POLYMERS;SOLUTIONS;NYLON;CHAINS;RHEOLOGY;SHEAR;VISCOSITY

 

数据来源: AIP

 

摘要:

Rheological and rheo‐optical properties are studied for homogeneous blends of the rodlike poly(1,4‐phenylene‐2,6‐benzobisthiazole), PBT, and poly(hexamethylene adipamide), nylon‐66. The linear recoverable creep compliance shows that the distribution of retardation times is similar for all the blends studied, though shifted on the time scale by large variation in the viscosity among the blends. A single‐integral (BKZ‐type) constitutive equation is found adequate to represent the dependence on shear rate of the nonlinear steady‐state viscosity, the recoverable compliance, and the flow birefringence (save for certain anomalous behavior at low shear rate in the latter case). Effects on the viscosity are discussed in terms of a simplified model for behavior when a characteristic rheological time constant is longer for the rodlike (PBT) than for the flexible chain (nylon‐66) component.

 

点击下载:  PDF (1256KB)



返 回