Rheological properties of rodlike polymers in solution. IV. Rheology of blends of nylon and a rodlike chain
作者:
C. S. Kim,
G. C. Berry,
期刊:
Journal of Rheology
(AIP Available online 1990)
卷期:
Volume 34,
issue 7
页码: 1011-1038
ISSN:0148-6055
年代: 1990
DOI:10.1122/1.550108
出版商: The Society of Rheology
关键词: Homogeneous blends;Rheology of blends;Rheo‐optical measurements;Retardation time;BKZ theory;Birefringence;ORGANIC POLYMERS;SOLUTIONS;NYLON;CHAINS;RHEOLOGY;SHEAR;VISCOSITY
数据来源: AIP
摘要:
Rheological and rheo‐optical properties are studied for homogeneous blends of the rodlike poly(1,4‐phenylene‐2,6‐benzobisthiazole), PBT, and poly(hexamethylene adipamide), nylon‐66. The linear recoverable creep compliance shows that the distribution of retardation times is similar for all the blends studied, though shifted on the time scale by large variation in the viscosity among the blends. A single‐integral (BKZ‐type) constitutive equation is found adequate to represent the dependence on shear rate of the nonlinear steady‐state viscosity, the recoverable compliance, and the flow birefringence (save for certain anomalous behavior at low shear rate in the latter case). Effects on the viscosity are discussed in terms of a simplified model for behavior when a characteristic rheological time constant is longer for the rodlike (PBT) than for the flexible chain (nylon‐66) component.
点击下载:
PDF
(1256KB)
返 回