Nitro group participation in the formation of heterocycles
作者:
Shyam Sunder,
Norton P. Peet,
期刊:
Journal of Heterocyclic Chemistry
(WILEY Available online 1979)
卷期:
Volume 16,
issue 1
页码: 33-37
ISSN:0022-152X
年代: 1979
DOI:10.1002/jhet.5570160108
出版商: Wiley‐Blackwell
数据来源: WILEY
摘要:
AbstractBenzoyl bromide (2‐nitrophenyl) hydrazone (2) was treated with sodium ethoxide and ethyl cyanoacetate and two unexpected products were obtained. These products were ultimately shown to be 6‐bromo‐3‐phenyl‐1,2,4‐benzotriazine (32) and 5‐bromo‐2‐phenylbenzoxazole (38), by comparison with authentic samples which were synthesized. A mechanism is presented for the formation of these two heterocyclic systems (
点击下载:
PDF
(383KB)
返 回