Chemical Reactions on Polymers. 111. Modification of Diene Polymers via the Ene Reaction with 4-Substituted-1,2,4-triazoline-3,5-diones
作者:
T.C. S. Chen,
GeorgeB. Butler,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 16,
issue 3
页码: 757-768
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108056822
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Various diene polymers have been modified at room temperature via the ene reaction with 4-substituted-1,2,4-triazoline-3,5-diones. The resulting modified polymers were characterized by means of IR spectroscopy, nuclear magnetic resonance, differential scanning calorimetry, and solubility tests. Physical properties measurements support the assumption that the highly-polar pendant urazole groups play an important role in both inter-molecular and intramolecular hydrogen bonding interaction, and accordingly give thermoplastic properties to the modified polymers. Changes in the thermal analysis and solubility character of the modified polymers agree fairly well with this assumption. The modified polymers remain soluble in suitable solvents because of the physical nature of the association between molecules.
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