An energetics approach to the analysis of molecular motions in polymeric solids
作者:
R.L. McCullough,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1974)
卷期:
Volume 9,
issue 1
页码: 97-139
ISSN:0022-2348
年代: 1974
DOI:10.1080/00222347408204541
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The feasibility of certain modes of intra-and intermolecular motion in polymeric solids are examined in terms of interaction energetics and geometrical constraints. Energy methods for determining equilibrium chain structures and stable deformation structures are reviewed. A systematic approach to the specification of explicit geometrical constraints in condensed phase polymeric systems is developed by matrix techniques. Combination rules are derived which provide straightforward means of constructing deformation structures for oriented polymers.
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