Vibronic intensities in the electronic spectra of transition-metal complex ions
作者:
R. Acevedo,
G. Diaz,
J.R. Letelier,
C.D. Flint,
期刊:
Molecular Physics
(Taylor Available online 1990)
卷期:
Volume 71,
issue 5
页码: 1063-1073
ISSN:0026-8976
年代: 1990
DOI:10.1080/00268979000102321
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The vibronic intensities of the vibronic origins due to the three odd-parity vibrational modes of the Γ8(2T2g) → Γ8(4A2g) electronic transition of the ReBr2-6ion are calculated using both crystal-field and ligand-polarization vibronic models. The crystal-field calculations is carried out using the closure approximation, and both models employ the double-group formalism. The vibronic intensity distribution is different for the two models, but by using reasonable values of the radial integrals and atomic charges, satisfactory agreement with experiment is achieved.
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