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Non‐linear effects of TMS capping on dimethyloctyl HPLC stationary phases

 

作者: S. A. Tomellini,   Shih‐Hsien Hsu,   S. D. Fazio,   R. A. Hartwick,  

 

期刊: Journal of High Resolution Chromatography  （WILEY Available online 1985）
卷期: Volume 8, issue 7  

页码: 337-340

 

ISSN:0935-6304

 

年代: 1985

 

DOI:10.1002/jhrc.1240080704

 

出版商: Wiley Subscription Services, Inc., A Wiley Company

 

关键词: Liquid chromatography, HPLC;Dimethyloctyl stationary phases;Trimethylsilyl capping agents

 

数据来源: WILEY

 

摘要:

AbstractCo‐bonding ligands on the same support to produce “blended” HPLC stationary phases is most commonly carried out in the form of capped reversed‐phase materials. Non‐additive retention properties were observed over a range of trimethylsilane/dimethyloctylsilane ratios. In addition, the increase in retention per mole of bonded trimethylsilane was greatest at the highest dimethyloctylsilane

 

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