Photoinduced Graft Copolymerization of Acrylic Acid-n-Butyl Acrylate on Polyvinyl Chloride
作者:
Wasaburo Kawai,
Taichi Ichihashi,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1974)
卷期:
Volume 8,
issue 4
页码: 805-818
ISSN:0022-233X
年代: 1974
DOI:10.1080/00222337408066399
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The photoinduced graft polymerization of acrylic acid and n-butyl acrylate on polyvinyl chloride or carbon monoxide-vinyl chloride copolymer by using benzophenone as a sensitizer was carried out. In graft polymerization of acrylic acid, the degree of grafting was low. However, graft polymerization of n-butyl acrylate or acrylic acid-n-butyl acrylate were higher than that of acrylic acid. Turbidimetry, DTA, and TGA of the graft polymer were examined. As the graft polymer was a weak polyacid, the pKawas estimated according to the Henderson equation, and the relationship between pKaand the acrylic acid unit content in the graft polymer was derived.
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