SOLVENT EXTRACTION OF NEPTUNIUM BY n-OCTYL(PHENYL)-N,N- DIISOBUTYLCARBAMOYLMETHYLPHOSPHINE OXIDE FROM NITRIC ACID SOLUTION CONTAINING HYDROGEN PEROXIDE
作者:
D. S. Wisnubroto,
S. Nagasaki,
Y. Enokida,
A. Suzuki,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1993)
卷期:
Volume 11,
issue 4
页码: 569-583
ISSN:0736-6299
年代: 1993
DOI:10.1080/07366299308918174
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Solvent extraction of Np with n -octyl ( pheny1) -N, N -diisobutylcarbamoylmethylphosphine oxide (CMPO) from HNO3solution containing H2O2was studied from the aspect of extraction rate. Neptunium initially in the pentavalent oxidation state can be extracted by CMPO even without the addition any redox agents, but the distribution is rather low. The H2O2was found to enhance the distribution ratio. The extraction rate was almost proportional to the 1.5-power of H2O2concentration. The dependence of the extraction rate on HNO3concentration was also examined. Reduction of Np(V) with H2O2occurs rapidly in the presence of CMPO. The extraction rate is not strongly affected by the presence of tri-n-butylphosphate in the organic phase. As a diluent, decalin gives a greater extraction rate than n-dodecane.
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