Influence of Liquid Crystallinity and Aggregation on Photo-orientation
作者:
Michael Rutloh,
Joachim Stumpe,
L. Stachanov,
Sergej Kostromin,
Valery Shibaev,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 352,
issue 1
页码: 149-157
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023172
出版商: Taylor & Francis Group
关键词: Photo-orientation;optical anisotropy;azobenzene;aggregation;liquid crystalline polyacrylate;photoisomerization;alignment
数据来源: Taylor
摘要:
The dependence of the Photo-orientation process on the liquid crystallinity and the molecular aggregation is studied. In the case of ordered films the photo-orientation is restricted, but this restriction can be overcome by a photochemical pre-treatment using UV light or by higher power density of the incident Vis light. The optical anisotropy increases with spacer length or the ordering tendency of the polymers.
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