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Basicity of o-aminomethylphenols in nonaqueous media

 

作者: A.B.Teitel'baum,   L.A.Kudryavtseva,   V.E.Bel'skii,   B.E.Ivanov,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 29, issue 10  

页码: 1571-1580

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00951216

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.The basicity of o-aminomethylphenols in nitromethane, acetonitrile, and ethanol is lower in comparison with benzylamines, which do not have any intramolecular hydrogen bonds.2.The influence of the intramolecular hydrogen bond on the basicity of the o-aminomethylphenols increases in the following series of solvents: ethanol

 

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