Thermodynamically Consistent Theory of Classical Liquid Structure and Inverse Problem of Extracting Pair Potential
作者:
N.H. March,
G. Senatore,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1984)
卷期:
Volume 13,
issue 4
页码: 285-292
ISSN:0031-9104
年代: 1984
DOI:10.1080/00319108408080787
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The direct correlation functionc(r)is divided into two parts, following the work of Kumaret al.One part,c(r)potential≡cp(r), contributes the entire compressibility and decays at largeras-(r)/KBT, with (r) the density independent pair potential. The definition ofcp(r) as–(r)/KBT{(1/6ρr2)∂2/∂ρ∂r[ρ2r3g(r)]{ is motivated by the condition of thermodynamic consistency, and for a hard core liquid leads tocp(r) small inside an atomic diameter.
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