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Monte Carlo Study of Binary Copolymerizations. 2. The Determination of Reactivity Ratios, Applications

 

作者: Ioan Moţoc,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1981)
卷期: Volume 15, issue 1  

页码: 85-93

 

ISSN:0022-233X

 

年代: 1981

 

DOI:10.1080/00222338108066432

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This paper discusses an improved and efficient version of the MEMØRY-7 computer program described in a previous paper. The program, called MEMØRY-7/1, implements a Monte Carlo algorithm to compute reactivity ratios in binary irreversible copolymerizations. For the copolymerization of acrylic acid and methyl acrylate, the computed r1, r2values (r1= 1.374, r2= 1.038) compare quite well with experimentally determined ones (r1= 1.4, r2= 1.0; Eldridge and Treloar).

 

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