Some investigations in the theory of open-shell ions
作者:
J.S. Griffith,
期刊:
Molecular Physics
(Taylor Available online 1960)
卷期:
Volume 3,
issue 5
页码: 477-483
ISSN:0026-8976
年代: 1960
DOI:10.1080/00268976000100511
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The basis of the theory of electric dipole intensities in centrosymmetric ions is critically examined. It is shown that the physical assumptions of one current version [3, 4, 5] of this theory are mathematically inconsistent and the necessary revision of the theory is given. It is also pointed out that excitations from odd parity filled shells into thedshell should give a significant, and usually negative, contribution to the intensities.
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