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Some investigations in the theory of open-shell ions

 

作者: J.S. Griffith,  

 

期刊: Molecular Physics  (Taylor Available online 1960)
卷期: Volume 3, issue 5  

页码: 477-483

 

ISSN:0026-8976

 

年代: 1960

 

DOI:10.1080/00268976000100511

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The basis of the theory of electric dipole intensities in centrosymmetric ions is critically examined. It is shown that the physical assumptions of one current version [3, 4, 5] of this theory are mathematically inconsistent and the necessary revision of the theory is given. It is also pointed out that excitations from odd parity filled shells into thedshell should give a significant, and usually negative, contribution to the intensities.

 

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