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The “Oriented Gas Model” and its Application to the Infrared Spectroscopy of Molecular Crystals

 

作者: JózefW. Rohleder,   Tadeusz Luty,  

 

期刊: Molecular Crystals  (Taylor Available online 1968)
卷期: Volume 5, issue 2  

页码: 145-163

 

ISSN:0369-1152

 

年代: 1968

 

DOI:10.1080/15421406808082936

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The real path of the polarized radiation in passing throughout an anisotropic crystal essentially depends on the orientation of the principal dielectric tensor axes with respect to the cleavage plane of the sample. Proper elucidation of this fact leads to new expressions for the dichroie ratio of a molecular crystal which contains terms connected both with the orientation of molecular transition moments and with the dielectric tensor axes as well. The agreement of the theory with experiment is illustrated in several examples.

 

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