Rheological behavior of polydimethylsiloxane/polyoxyethylene blends in the melt. Emulsion model of two viscoelastic liquids
作者:
D. Graebling,
R. Muller,
期刊:
Journal of Rheology
(AIP Available online 1990)
卷期:
Volume 34,
issue 2
页码: 193-205
ISSN:0148-6055
年代: 1990
DOI:10.1122/1.550123
出版商: The Society of Rheology
关键词: Dynamic measurements;Linear viscoelasticity;Polymer melt rheology;Immiscible polymer blends;Oldroyd’s emulsion model;RHEOLOGY;RELAXATION;BINARY MIXTURES;VISCOELASTICITY;MELTS;POLYETHYLENES;METHYL COMPOUNDS;SILOXANES
数据来源: AIP
摘要:
The linear viscoelastic behavior of two‐phase polymer blends in the melt is characterized by high values of storage modulus at low frequencies and by long relaxation times. The variation of dynamic moduli with frequency could be explained with an emulsion model as developed by Oldroyd. This model allows us to take in account the viscoelastic behavior of each phase, as well as characteristic parameters of the blends like volume fraction, interfacial tension, and size of inclusions. Experimental results on polydimethylsiloxane/polyoxyethylene‐diol blends are found to be in good accordance with Oldroyd’s emulsion law. The terminal relaxation process of the blend can be assigned to the geometric relaxation of the inclusions.
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