首页   按字顺浏览 期刊浏览 卷期浏览 Rheological behavior of polydimethylsiloxane/polyoxyethylene blends in the melt. Emulsi...
Rheological behavior of polydimethylsiloxane/polyoxyethylene blends in the melt. Emulsion model of two viscoelastic liquids

 

作者: D. Graebling,   R. Muller,  

 

期刊: Journal of Rheology  (AIP Available online 1990)
卷期: Volume 34, issue 2  

页码: 193-205

 

ISSN:0148-6055

 

年代: 1990

 

DOI:10.1122/1.550123

 

出版商: The Society of Rheology

 

关键词: Dynamic measurements;Linear viscoelasticity;Polymer melt rheology;Immiscible polymer blends;Oldroyd’s emulsion model;RHEOLOGY;RELAXATION;BINARY MIXTURES;VISCOELASTICITY;MELTS;POLYETHYLENES;METHYL COMPOUNDS;SILOXANES

 

数据来源: AIP

 

摘要:

The linear viscoelastic behavior of two‐phase polymer blends in the melt is characterized by high values of storage modulus at low frequencies and by long relaxation times. The variation of dynamic moduli with frequency could be explained with an emulsion model as developed by Oldroyd. This model allows us to take in account the viscoelastic behavior of each phase, as well as characteristic parameters of the blends like volume fraction, interfacial tension, and size of inclusions. Experimental results on polydimethylsiloxane/polyoxyethylene‐diol blends are found to be in good accordance with Oldroyd’s emulsion law. The terminal relaxation process of the blend can be assigned to the geometric relaxation of the inclusions.

 

点击下载:  PDF (533KB)



返 回