首页   按字顺浏览 期刊浏览 卷期浏览 An algorithm for fast determination of complex moduli
An algorithm for fast determination of complex moduli

 

作者: Grethe Winther,   Ole Kramer,   Jeppe C. Dyre,  

 

期刊: Journal of Rheology  (AIP Available online 1994)
卷期: Volume 38, issue 4  

页码: 1179-1193

 

ISSN:0148-6055

 

年代: 1994

 

DOI:10.1122/1.550590

 

出版商: The Society of Rheology

 

关键词: POLYMERS;COMPUTERIZED SIMULATION;FOURIER ANALYSIS;ALGORITHMS;OSCILLATIONS;TRANSIENTS;STRESS−STRAIN RELATION;VISCOELASTICITY

 

数据来源: AIP

 

摘要:

Traditionally, the complex modulus is determined by Fourier analysis of steady state oscillatory data. However, steady state is not obtained immediately and data from the first period of oscillation must therefore be discarded. In the present work a recursive analysis algorithm for the determination of complex moduli from oscillatory data of the first period, which includes a transient response alongside the steady state response, is derived. The algorithm is based on Boltzmann’s principle of superposition. At any given time, the analysis algorithm provides the best possible estimate of the complex modulus on the basis of the information available at that time, i.e., the stress and strain history. The analysis algorithm has been tested on simulated data from a mathematical model of an amorphous polymer. The tests show that the new analysis algorithm can determine the dynamic mechanical properties with very good accuracy from oscillatory data of the first period, where Fourier analysis fails. Thus, use of the new algorithm allows a reduction of the experiment time by a factor of 2 for experiments with a sufficiently high signal‐to‐noise ratio to avoid averaging over several periods. This reduction of the measurement time is particularly important for experiments at very low frequencies where the long measurement times seriously limit the number of runs per day.

 

点击下载:  PDF (865KB)



返 回