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Stabilization of block copolymer micelles by UV and fast electron radiation

 

作者: Zdeněk Tuzar,   Bohumil Bednář,   Čestmír Koňák,   Miroslav Kubín,   Štěpánka Svobodová,   Karel Procházka,  

 

期刊: Die Makromolekulare Chemie  (WILEY Available online 1982)
卷期: Volume 183, issue 2  

页码: 399-408

 

ISSN:0025-116X

 

年代: 1982

 

DOI:10.1002/macp.1982.021830211

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractMicelles of a block copoymer poly(styrene/butadiene/styrene) with cores consisting of polybutadiene blocks were stabilized in dilute solutions by UV radiation in the presence of a photo‐initiator and also by fast electrons, and micelles of a block copolymer poly(styrene/ethene‐co‐1‐butene/styrene) with cores formed by the aliphatic blocks were stabilized by fast electrons, in dilute solutions. Stabilization of micelles, i. e., crosslinking of the chains in micellar cores as well as the properties of stabilized micelles were studied by conventional light scattering, by light scattering photon correlation spectroscopy and by gel permeation chromat

 

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