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Preparation of a Monochiral Terpenoid SynthonfFrom Carvone Using a Stereoselective Intramolecular Nitrile Oxide Cycloaddition

 

作者: J.-P. Gesson,   S.A. M. Nieuwenhuis,   B. Renoux,  

 

期刊: Natural Product Letters  （Taylor Available online 1993）
卷期: Volume 2, issue 2  

页码: 129-135

 

ISSN:1057-5634

 

年代: 1993

 

DOI:10.1080/10575639308043797

 

出版商: Taylor & Francis Group

 

关键词: terpene;carvone;nitrile oxide;cycloaddition

 

数据来源: Taylor

 

摘要:

Starting from (-)-carvone, two consecutive regio- and stereospecific alkylations followed by a stereoselective INOC reaction, carried out either on a nitro derivative or on the corresponding oxime, afford, in few overall steps, a monochiral bicyclic synthon which may be used for the preparation of terpenes such as aphidicolin.

 

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