Petrographical and mineral chemical data are given for the eclogites which occur in the garnet‐kyanite micaschists of the Penninic Dora‐Maira Massif between Brossasco, Isasca and Martiniana (Italian Western Alps) and for a sodic whiteschist associated with the pyrope‐coesite whiteschists of Martiniana. The Brossasco‐Isasca (BI) eclogites are fine grained, foliated and often mica‐rich rocks with a strong preferred orientation of omphacite crystals and white micas. Porphyroblasts of hornblende are common in some varieties, whilst zoisite and kyanite occur occasionally in pale green varieties associated with leucocratic layers with quartz, jadeite and garnet. These features differentiate the BI eclogites from the eclogites that occur in other continental units of the Western Alps, which all belong to type C. Garnet, sodic pyroxene and glaucophane are the major minerals in the sodic whiteschist.Sodic pyroxene in the eclogites is an omphacite often close to Jd50Di50, with very little acmite and virtually no AlIV, and impure jadeite in the leucocratic layers and in the sodic whiteschist. Garnet is almandine with 20–30 mol. % for each of the pyrope and grossular components in the eclogites and a pyrope‐rich variety in the sodic whiteschist. White mica is a variably substituted phengite, and paragonite apparently only occurs as a replacement product of kyanite. Amphibole is hornblende in the eclogites, but the most magnesian glaucophane yet described in the sodic whiteschist. Quartz pseudomorphs of coesite were found occasionally in a few pyroxenes and garnets.TheP‐Tconditions during the VHP event are constrained in the eclogites by reactions which define a field ranging from 27–28 kbar to 35 kbar and from 680 to 750° C. These temperatures are consistent with the results of garnet‐pyroxene and garnet‐phengite geothermometry which suggest that the eclogites may have equilibrated at around 700° C. In the sodic whiteschist pressures ranging from 29 to 35 kbar can be deduced from the stability of the jadeite‐pyrope garnet‐glaucophane compatibility. As in the eclogites water activity must have been low. Such conditions are close to theP‐Tvalues estimated for the early Alpine recrystallization of the pyrope‐coesite rock and, like petrographical and mineralogical features, set aside the BI eclogites from the other eclogites of the Western Alps, instead indicating a close similarity to some of the eclogite bodies occurring in the Adula nappe of the Central Alps. An important corollary is that glaucophane stability, at least in Na‐ and Mg‐rich compositions and under very high pressures, may extend up to 700° C, in agreement with the HT stability lim