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Chemical transformations of 1,1-dichloroalkanes

 

作者: E.I.Vasll'eva,   R.Kh.Freiduria,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 10, issue 6  

页码: 969-971

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00909167

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.The action of nucleophilic and electrophilic reagents on the dichloromethyl group was studied on the example of 1,1-dichloroheptane.2.The dichloromethyl group is more inert toward the action of nucleophilic reagents than the chloromethyl group; only under the action of such strong nucleophiles as sodium thiophenolate could both of the chlorine atoms be replaced.3.The dichloromethyl group, in contrast to the trichloromethyl group, isinert toward the action of such electrophilic reagents as concd. sulfuric and anhydrous nitric acids. However, compounds containing the dichloromethyl group are capable of condensing with benzene in the presence of aluminum chloride.

 

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