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Incoherent scattering law for dynamically independent molecular and intramolecular reorientations in (CH3)3NHCl

 

作者: M. Schlaak,  

 

期刊: Molecular Physics  (Taylor Available online 1977)
卷期: Volume 33, issue 1  

页码: 125-131

 

ISSN:0026-8976

 

年代: 1977

 

DOI:10.1080/00268977700103101

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A jump model is developed which describes simultaneous, dynamically uncorrelated reorientational motions of a proton about two different threefold axes. For the spectrum of quasielastic neutron scattering a superposition of three lorentzians with linewidths of 1/τ1, 1/τ2, and 1/τ*=1/τ1+ 1/τ2is obtained as quasielastic broadening. The model is applied to describe the reorientations of the cation (CH3)3NH+and of the CH3groups in (CH3)3NH+Cl-.

 

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